In
this continuation of Physical Chemistry, we will use the quantum mechanics
we learned last semester to develop concepts in thermodynamics
and kinetics. The course will begin with an introduction to statistical
mechanics, which forms the bridge from quantum phenomena to the macroscopic
world of thermodynamics. We will discuss the laws of thermodynamics,
including energy, enthalpy, entropy, and the free energy. These thermodynamic
concepts will be used in chemical situations including a discussion
of spontaneous processes and equilibrium. As we progress we will use
the statistical concepts to elucidate thermodynamic ideas. We will then
discuss chemical dynamics including the dynamics of gases, kinetics,
and activation complex theory.
The course will be run as a combination of guided inquiry and lecture/discussion
mode. Which approach we use will depend on the material to be
covered. It is extremely important that you try to keep abreast of the
material; an hour or so each night is better than ten hours the day
before a test. You should always attempt to rephrase a definition or
concept in your own words. By doing this, you will have a better understanding
of the material.
You will gain practical experience in the
experimental aspects of these concepts in the laboratory. A list of
experiments is posted on the 302 labs page
You will be exposed to a number of mathematical
tools this semester, some of which may be new to you. Please ask
for help if you do not understand these ideas. I will try to minimize
the use of mathematics for mathematics' sake. You will need to
be familiar with algebra, simple derivatives and simple integrals. We
will be using Mathcad for manipulations that are more complicated. Do
not lose sight of the chemistry because of the mathematics!
